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当前位置:首页 > 技术文章 > 谷物、干辣椒中398种农药残留快速前处理的质谱法应用方案

谷物、干辣椒中398种农药残留快速前处理的质谱法应用方案

更新时间:2024-05-15      点击次数:175

1. 方法概述

本检验方法适用于谷类、干豆类、干辣椒等食品中373项农药多重残留分析 。

 

2. 检验方法:

样品采用一步法快速萃取柱(FaPEx-cer)净化后,以液相色谱串级质谱仪(LC/MS/MS)及气相色谱串级质谱仪(GC/MS/MS)外标法分析。

 

3.设备:

3.1 液相色谱串级质谱仪:

3.2 离子源:电喷雾电离源(ESI) 。

3.3色谱柱:CORTECS UPLC®  ,C18,1.6 µm,内径2.1 mm ×  10 cm,或 同级品 。

3.4保护柱:CORTECS UPLC®  ,C18,1.6 µm,内径2.1 mm × 5 mm , 或同级品 。

3.5气相色谱串联质谱仪:

3.6离子源:电子轰击源(EI) 。

3.7色谱柱:DB-5MS UI毛细管,内膜厚度0.25 μm,内径0.25 mm×30 m ,或同级品。

 

3. 前处理操作步骤:

 

3.1.粉碎

谷类、干豆类、干辣椒类样品以粉碎机磨粉均质后检体取适量进行下述萃取及净化步骤,若无法于当天进行分析,应保存于 -20℃中 。

 

3.2. 干豆类、谷类及干辣椒类:

取均质后称重约0.5 g,置于离心管中,先加入去离子水1mL,混匀并静置10分钟再加入含1%醋酸之乙腈溶液5 mL,盖上离心管盖,随即旋涡混匀30秒后,将萃取液注入一步法净化柱FaPEx-cer,流速控制为1滴/秒,收集全部流出液,作为检液原液。

取检液原液1 mL , 以滤膜过滤,上机LC/MS/MS分析。

另取检液原液1 mL,以氮气吹至刚干,残留物以丙酮:正己烷(1:1, v/v) 1mL溶解,混合均匀,经滤膜过滤,上机GC/MS/MS分析。

 

4.仪器分析条件

4.1 液相层析串联质谱分析测定条件:

移动相溶液:A液与B液以下列条件进行梯度分析

时间(min)

A (%)

B (%)

0.0  2.0

99  50

1  50

2.0  8.0

50  30

50  70

8.0  10.0

30  1

70  99

10.0  13.0

1  1

99  99

13.0  13.5

1  99

99  1

13.5  15.0

99  99

1  1

移动相流速:0.3 mL/min 。

注入量:5 μL 。

毛细管电压(Capillary voltage) :

电洒离子化正离子(ESI+)采用3.5 kV ,

电洒离子化负离子(ESI-)采用1.6 kV 。

离子源温度(Ion source temperature):150°C 。

溶媒挥散温度(Desolvation temperature):450°C 。

进样锥气体流速(Cone gas flow):30 L/hr 。

溶媒挥散流速(Desolvation flow):900 L/hr 。

侦测模式:多重反应侦测(multiple reaction monitoring, MRM)。

 

4.2 GC/MS/MS :气相层析串联质谱分析测定条件:

层析管:DB-5MSUI毛细管,内膜厚度0.25 μm,内径0.25 mm × 30 m。

层析管温度:初温:60°C, 1 min;

升温速40°C/min;

中温:170°C;

升温速10°C/min;

终温:310°C,2.25 min 。

移动相流速:氦气,1 mL/min 。

注入器温度(Injector temperature):280°C 。

注入模式:不分流(splitless) 。

注入量:1 μL 。

离子化模式:电子撞击游离(EI),70 eV 。

离子源温度:300°C 。

侦测模式:多重反应侦测,侦测离子对及碰撞能量如表三。

 

1:芬普尼之基质匹配检量线制作时,选择适当之标准溶液添加 。

2:上述测定条件分析不适时,可依所使用之仪器,设定适合条件。

 

5、药剂清单(回收率等结果,联络索取)

编号

英文名称

中文名称

分析方法

1

Abamectin

阿维菌素

LC-MS/MS

2

Acephate

乙酰甲胺lin磷

LC-MS/MS

3

Acetamiprid

啶虫脒

LC-MS/MS

4

Acibenzolar-S-methyl

阿拉酸式苯-S-甲基

LC-MS/MS

5

Aldicarb

涕灭wei威

LC-MS/MS

6

Aldicarbsulfone

涕灭wei威砜

LC-MS/MS

7

Aldicarbsulfoxide

涕灭wei威亚砜

LC-MS/MS

8

Alloxydim(sodium)

禾草灭

LC-MS/MS

9

Ametoctradin

唑嘧菌胺

LC-MS/MS

10

Ametryn

莠灭净

LC-MS/MS

11

Amisulbrom

吲唑磺菌胺

LC-MS/MS

12

Atrazine

莠去津

LC-MS/MS

13

Azoxystrobin

嘧菌酯

LC-MS/MS

14

Benalaxyl

苯霜灵

LC-MS/MS

15

Bendiocarb

恶虫威

LC-MS/MS

16

Benfuracarb

丙硫克百wei威

LC-MS/MS

17

Bensulfuron-methyl

苄嘧磺隆

LC-MS/MS

18

Benthiazole

苯噻硫氰

LC-MS/MS

19

Bifenazate

联苯肼酯

LC-MS/MS

20

Boscalid

啶酰菌胺

LC-MS/MS

21

Bufencarb

合杀威

LC-MS/MS

22

Buprofezin

噻嗪酮

LC-MS/MS

23

Butocarboxim

丁酮威

LC-MS/MS

24

Carbaryl

甲萘威

LC-MS/MS

25

Carbendazim

多菌灵

LC-MS/MS

26

Carbofuran

克百wei威

LC-MS/MS

27

3-ketoCarbofuran

3-酮基呋nan喃丹

LC-MS/MS

28

3-OHCarbofuran

3-羟基呋nan喃丹

LC-MS/MS

29

Carbosulfan

丁硫克bai百威

LC-MS/MS

30

Carfentrazone-ethyl

唑草酮

LC-MS/MS

31

Carpropamid

加普胺

LC-MS/MS

32

Chlorantraniliprole

氯虫苯甲酰胺

LC-MS/MS

33

Chlorfluazuron

氟啶脲

LC-MS/MS

34

Chromafenozide

环虫酰肼

LC-MS/MS

35

Cinern I

除虫菊精 I

LC-MS/MS

36

Cinern II

除虫菊精 II

LC-MS/MS

37

Cinosulfuron

醚磺隆

LC-MS/MS

38

Clethodim

烯草酮

LC-MS/MS

39

Clofentezine

四螨嗪

LC-MS/MS

40

Clomazone

异恶草酮

LC-MS/MS

41

Clomeprop

氯甲酰草胺

LC-MS/MS

42

Clothianidin

噻虫胺

LC-MS/MS

43

Cyanazine

氰草津

LC-MS/MS

44

Cyazofamid

氰霜唑

LC-MS/MS

45

Cyclosulfamuron

环丙嘧磺隆

LC-MS/MS

46

Cycloxydim

噻草酮

LC-MS/MS

47

Cyflufenamid

环氟菌胺

LC-MS/MS

48

Cyflumetofen

丁氟螨酯

LC-MS/MS

49

Cymoxanil

霜脲氰

LC-MS/MS

50

Cyprodinil

嘧菌环胺

LC-MS/MS

51

Demeton-S-methyl

甲基内xi吸磷

LC-MS/MS

52

Dicrotophos

百治lin磷

LC-MS/MS

53

Dimethenamid

二甲吩草胺

LC-MS/MS

54

Dimethoate

乐果

LC-MS/MS

55

Dimethomorph

烯酰吗啉

LC-MS/MS

56

Dinotefuran

呋虫胺

LC-MS/MS

57

Diuron

敌草隆

LC-MS/MS

58

Dymron

杀草隆

LC-MS/MS

59

EmamectinbenzoateB1a

甲氨基阿维菌素B1a苯甲酸盐

LC-MS/MS

60

EmamectinbenzoateB1b

甲氨基阿维菌素B1b苯甲酸盐

LC-MS/MS

61

Ethiprole

乙虫腈

LC-MS/MS

62

Ethirimol

乙嘧酚

LC-MS/MS

63

Etoxazole

乙螨唑

LC-MS/MS

64

Famoxadone

噁唑菌酮

LC-MS/MS

65

Fenamiphos

苯线lin磷

LC-MS/MS

66

Fenazaquin

喹螨醚

LC-MS/MS

67

Fenbutatin-oxide

苯丁锡

LC-MS/MS

68

Fenhexamid

环酰菌胺

LC-MS/MS

69

Fenobucarb

仲丁威

LC-MS/MS

70

Fenothiocarb

苯硫威

LC-MS/MS

71

Fenoxanil

稻瘟酰胺

LC-MS/MS

72

Fenoxycarb

苯氧威

LC-MS/MS

73

Fenpyroximate

唑螨酯

LC-MS/MS

74

Fenthion

倍硫lin磷

LC-MS/MS

75

Ferimzone

嘧菌腙

LC-MS/MS

76

Flazasulfuron

啶嘧黄隆

LC-MS/MS

77

Flonicamid

氟啶虫酰胺

LC-MS/MS

78

Fluazifop-P-butyl

吡氟禾草灵

LC-MS/MS

79

Fludioxonil

咯菌腈

LC-MS/MS

80

Flufenoxuron

氟虫脲

LC-MS/MS

81

Fluopicolide

氟吡菌胺

LC-MS/MS

82

Fluopyram

氟吡菌酰胺

LC-MS/MS

83

Flupyradifurone

氟吡呋喃酮

LC-MS/MS

84

Flusilazole

氟硅唑

LC-MS/MS

85

Flutriafol

粉唑醇

LC-MS/MS

86

Formetanate

伐虫脒

LC-MS/MS

87

Fosthiazate

噻唑磷

LC-MS/MS

88

Furametpyr

呋吡菌胺

LC-MS/MS

89

Haloxyfop-methyl

氟吡甲禾灵

LC-MS/MS

90

Hexaconazole

己唑醇

LC-MS/MS

91

Hexaflumuron

氟铃脲

LC-MS/MS

92

Hexythiazox

噻螨酮

LC-MS/MS

93

Imazalil

抑霉唑

LC-MS/MS

94

Imidacloprid

吡虫啉

LC-MS/MS

95

Indoxacarb

茚虫威

LC-MS/MS

96

Iprovalicarb

缬霉威

LC-MS/MS

97

Isazofos

氯唑lin磷

LC-MS/MS

98

Isoprocarb

异丙威

LC-MS/MS

99

Isopyrazam

吡唑萘菌胺

LC-MS/MS

100

Isouron

异恶隆

LC-MS/MS

101

Isoxaflutole

异恶唑草酮

LC-MS/MS

102

JasmolinI

茉酮菊素I

LC-MS/MS

103

JasmolinII

茉酮菊素II

LC-MS/MS

104

Linuron

利谷隆

LC-MS/MS

105

Mandipropamid

双炔酰菌胺

LC-MS/MS

106

Mecarbam

灭蚜磷

LC-MS/MS

107

Mepanipyrim

嘧菌胺

LC-MS/MS

108

Metaflumizone

氰氟虫腙

LC-MS/MS

109

Metalaxyl

甲霜灵

LC-MS/MS

110

Metconazole-cis

顺式-叶菌唑

LC-MS/MS

111

Methamidophos

甲胺lin磷

LC-MS/MS

112

Methiocarb

甲硫威

LC-MS/MS

113

Methomyl

灭多威

LC-MS/MS

114

Methoprene

烯虫酯

LC-MS/MS

115

Methoxyfenozide

甲氧虫酰肼

LC-MS/MS

116

Metobromuron

溴谷隆

LC-MS/MS

117

Metolcarb

速灭wei威

LC-MS/MS

118

Metrafenone

苯菌酮

LC-MS/MS

119

Metribuzin

嗪草酮

LC-MS/MS

120

Mevinphos

速灭磷

LC-MS/MS

121

Monocrotophos

久效lin磷

LC-MS/MS

122

MPMC(Xylylcarb)

灭杀威

LC-MS/MS

123

Norflurazon

哒草伏

LC-MS/MS

124

Novaluron

氟酰脲

LC-MS/MS

125

Omethoate

氧乐果

LC-MS/MS

126

Oxamyl

杀线威

LC-MS/MS

127

Oxycarboxin

氧化萎锈灵

LC-MS/MS

128

Oxydemeton-Methyl

亚砜磷

LC-MS/MS

129

Pencycuron

戊菌隆

LC-MS/MS

130

Penoxsulam

五氟磺草胺

LC-MS/MS

131

Phosphamidon

磷an胺

LC-MS/MS

132

Phoxim

辛硫lin磷

LC-MS/MS

133

Piperonylbutoxide

增效醚

LC-MS/MS

134

Pirimicarb

抗蚜wei威

LC-MS/MS

135

Pretilachlor

丙草胺

LC-MS/MS

136

Probenazole

烯丙苯噻唑

LC-MS/MS

137

Prochloraz

咪酰胺

LC-MS/MS

138

Profenophos

丙溴磷

LC-MS/MS

139

Promecarb

猛杀威

LC-MS/MS

140

Propamocarb hydrochloride

霜霉威盐酸盐

LC-MS/MS

141

Propanil

敌稗

LC-MS/MS

142

Propargite

炔螨特

LC-MS/MS

143

Propoxur

残杀威

LC-MS/MS

144

Proquinazid

丙氧喹啉

LC-MS/MS

145

Pymetrozine

吡蚜酮

LC-MS/MS

146

Pyraclostrobin

吡唑醚菌酯

LC-MS/MS

147

Pyrazosulfuron-ethyl

吡嘧磺隆

LC-MS/MS

148

PyrethrinI

除虫菊素I

LC-MS/MS

149

PyrethrinII

除虫菊素II

LC-MS/MS

150

Pyribencarb

吡菌苯威

LC-MS/MS

151

Pyridaben

哒螨灵

LC-MS/MS

152

Pyrifluquinazon

吡啶喹唑啉

LC-MS/MS

153

Pyridate

哒草特

LC-MS/MS

154

Pyrifenox

碇斑肟

LC-MS/MS

155

Quinoxyfen

喹氧灵

LC-MS/MS

156

Quizalofop-ethyl

喹禾灵

LC-MS/MS

157

Rotenone

鱼藤酮

LC-MS/MS

158

Saflufenacil

苯嘧磺草胺

LC-MS/MS

159

Sethoxydim

烯禾啶

LC-MS/MS

160

Simazine

西玛津

LC-MS/MS

161

SpinetoramJ

乙基多杀菌素 J

LC-MS/MS

162

SpinetoramL

乙基多杀菌素 L

LC-MS/MS

163

SpinosadA
(spinosynA)

 多杀霉素A

LC-MS/MS

164

SpinosadD
(spinosynD)

 多杀霉素D

LC-MS/MS

165

Spirodiclofen

螺螨酯

LC-MS/MS

166

Spiromesifen

螺甲螨酯

LC-MS/MS

167

Spirotetramat

螺虫乙酯

LC-MS/MS

168

Sulfoxaflor

氟啶虫胺腈

LC-MS/MS

169

Tebufenozide

虫酰肼

LC-MS/MS

170

Tebufenpyrad

吡螨胺

LC-MS/MS

171

Tepraloxydim

得杀草

LC-MS/MS

172

Thiabendazole

噻菌灵

LC-MS/MS

173

Thiacloprid

噻虫啉

LC-MS/MS

174

Thiamethoxam

噻虫嗪

LC-MS/MS

175

Thiobencarb

禾草丹

LC-MS/MS

176

Thiodicarb

硫双威

LC-MS/MS

177

Thiofanox

久效wei威砜

LC-MS/MS

178

Tolfenpyrad

唑虫酰胺

LC-MS/MS

179

Tolyfluanid

对甲抑菌灵

LC-MS/MS

180

Trichlorfon

敌百chong虫

LC-MS/MS

181

Tricyclazole

三环唑

LC-MS/MS

182

Trifloxystrobin

肟菌酯

LC-MS/MS

183

Triforine

嗪氨灵

LC-MS/MS

184

Vamidothion

蚜灭磷

LC-MS/MS

185

XMC(Macbal)

二甲威

LC-MS/MS

186

Zoxamide

苯酰菌胺

LC-MS/MS

187

Acequinocyl-
hydroxyl

羟基灭螨醌

LC-MS/MS

188

Bentazone

灭草松

LC-MS/MS

189

Diflubenzuron

除虫脲

LC-MS/MS

190

Fipronil

氟虫腈

LC-MS/MS

191

Fipronil-sulfone

氟虫腈砜

LC-MS/MS

192

Fluazinam

氟啶胺

LC-MS/MS

193

Flubendiamide

氟苯虫酰胺

LC-MS/MS

194

Lufenuron

虱螨脲

LC-MS/MS

195

Penthiopyrad

吡噻菌胺

LC-MS/MS

196

Teflubenzuron

氟苯脲

LC-MS/MS

197

Acetochlor

乙草胺

GC-MSMS

198

Acrinathrin

氟酯菊酯

GC-MSMS

199

Alachlor

甲草胺

GC-MSMS

200

Aldrin

艾氏ji剂

GC-MSMS

201

Allethrin

丙烯菊酯

GC-MSMS

202

Azinphos-methyl

保棉磷

GC-MSMS

203

Benfluralin

苯氟拉林

GC-MSMS

204

α-BHC

α-六六六

GC-MSMS

205

β-BHC

β-六六六

GC-MSMS

206

γ-BHC(Lindane)

γ-六六六

GC-MSMS

207

δ-BHC

δ-六六六

GC-MSMS

208

Bifenox

甲羧除草醚

GC-MSMS

209

Bifenthrin

联苯菊酯

GC-MSMS

210

Bitertanol

联苯三唑醇

GC-MSMS

211

Bromacil

除草定

GC-MSMS

212

Bromophos-ethyl

乙基溴硫磷

GC-MSMS

213

Bromophos-methyl

甲基溴硫磷

GC-MSMS

214

Bromopropylate

溴螨酯

GC-MSMS

215

Bromuconazole

糠菌唑

GC-MSMS

216

Bupirimate

乙嘧酚磺酸酯

GC-MSMS

217

Butachlor

丁草胺

GC-MSMS

218

Butralin

仲丁灵

GC-MSMS

219

Cadusafos

硫线磷

GC-MSMS

220

Carbophenothion

三硫lin磷

GC-MSMS

221

Chinomethionat

灭螨猛

GC-MSMS

222

cis-Chlordane

-氯丹

GC-MSMS

223

trans-Chlordane

-氯丹

GC-MSMS

224

Chlorfenapyr

虫螨腈

GC-MSMS

225

Chloropropylate

氯丙基

GC-MSMS

226

Chlorothalonil

百菌清

GC-MSMS

227

Chlorpropham

氯苯胺灵

GC-MSMS

228

Chlorpyrifos

毒死蜱

GC-MSMS

229

Chlorpyrifos-methyl

甲基毒死蜱

GC-MSMS

230

Chlorthal-dimethyl

氯酞酸二甲酯

GC-MSMS

231

Chlozolinate

克氯得

GC-MSMS

232

CPMC(Etrofol)

害朴威

GC-MSMS

233

Cyanofenphos

氰硫磷

GC-MSMS

234

Cyanophos

杀螟腈

GC-MSMS

235

Cyfluthrin

氟氯氰菊酯

GC-MSMS

236

Cyhalofop-butyl

氰氟草脂

GC-MSMS

237

λ-Cyhalothrin

高效氯氟氰菊酯

GC-MSMS

238

Cypermethrin

氯氰菊酯

GC-MSMS

239

α-cypermethrin

α-氯氰菊酯

GC-MSMS

240

Cyproconazole

环丙唑醇

GC-MSMS

241

o,p’-DDD

o,p’-DDD

GC-MSMS

242

o,p’-DDE

o,p’-DDE

GC-MSMS

243

o,p'-DDT

o,p'-DDT

GC-MSMS

244

p,p’-DDE

p,p’-DDE

GC-MSMS

245

p,p’-DDT

p,p’-DDT

GC-MSMS

246

p,p'-DDD

p,p'-DDD

GC-MSMS

247

Deltamethrin

溴氰菊酯

GC-MSMS

248

Diazinon

二嗪磷

GC-MSMS

249

Dichlorvos

敌敌wei畏

GC-MSMS

250

Dicloran

氯硝胺

GC-MSMS

251

Dicofol

三氯杀man螨醇

GC-MSMS

252

Dicofol(DCBP)

o,p'-三氯杀man螨醇

GC-MSMS

253

Dieldrin

狄氏ji剂

GC-MSMS

254

Difenoconazole

苯醚甲环唑

GC-MSMS

255

2,6-Diisopropylnaphthalene
(2,6-DIPN)

2,6-二异丙基萘

GC-MSMS

256

Dimethipin

噻节因

GC-MSMS

257

Diniconazole

烯唑醇

GC-MSMS

258

Dinitramine

敌乐胺

GC-MSMS

259

Diphenamid

二苯胺

GC-MSMS

260

Diphenylamine

二苯胺

GC-MSMS

261

Disulfoton

乙拌lin磷

GC-MSMS

262

Ditalimfos

灭菌磷

GC-MSMS

263

Dithiopyr

氟硫草定

GC-MSMS

264

Edifenphos

敌瘟磷

GC-MSMS

265

“-Endosulfan

硫丹

GC-MSMS

266

β-Endosulfan

β-硫丹

GC-MSMS

267

Endosulfan-sulfate

硫丹硫酸酯

GC-MSMS

268

Endrin

异狄氏ji剂

GC-MSMS

269

EPN

苯硫磷

GC-MSMS

270

Epoxiconazole

氟环唑

GC-MSMS

271

Esfenvalerate

S-氰戊ju菊酯

GC-MSMS

272

Ethion

乙硫lin磷

GC-MSMS

273

Ethoprophos

灭线lin磷

GC-MSMS

274

Etofenprox

醚菊酯

GC-MSMS

275

Etridiazole

 氯唑灵

GC-MSMS

276

Etrimfos

乙嘧硫磷

GC-MSMS

277

Fenarimol

氯苯嘧啶醇

GC-MSMS

278

Fenbuconazole

腈苯唑

GC-MSMS

279

Fenitrothion

杀螟硫磷

GC-MSMS

280

Fenoxaprop-ethyl

精噁唑禾草灵

GC-MSMS

281

Fenpropathrin

甲氰菊ju酯

GC-MSMS

282

Fenpropimorph

丁苯吗啉

GC-MSMS

283

Fensulfothion

苯磺硫磷

GC-MSMS

284

Fenvalerate

氰戊菊ju酯

GC-MSMS

285

Flucythrinate

氟氰戊菊ju酯

GC-MSMS

286

Fluensulfone

氟砜灵

GC-MSMS

287

Fluroxypyr-meptyl

氟草烟

GC-MSMS

288

Flutolanil

氟酰胺

GC-MSMS

289

Fluvalinate

氟胺氰菊酯

GC-MSMS

290

Fluxapyroxad

氟唑菌酰胺

GC-MSMS

291

Fonofos

地虫磷

GC-MSMS

292

Formothion

安硫磷

GC-MSMS

293

Fthalide

四氯苯酞

GC-MSMS

294

Halfenprox

苄螨醚

GC-MSMS

295

Heptachlor

七氯

GC-MSMS

296

Heptachlorepoxide

环氧七氯

GC-MSMS

297

Heptenophos

庚烯磷

GC-MSMS

298

Hexazinone

环嗪酮

GC-MSMS

299

Imibenconazole

亚胺唑

GC-MSMS

300

Iprobenfos

异稻瘟wen净

GC-MSMS

301

Iprodione

异菌脲

GC-MSMS

302

Isofenphos

异丙胺磷

GC-MSMS

303

Isoprothiolane

稻瘟灵

GC-MSMS

304

Isotianil

异噻菌胺

GC-MSMS

305

Isoxathion

异恶硫磷

GC-MSMS

306

Kresoxim-methyl

醚菌酯

GC-MSMS

307

Malathion

马拉硫liu磷

GC-MSMS

308

Mefenacet

苯噻酰草胺

GC-MSMS

309

Mephosfolan

甲氧麻黄huang酮

GC-MSMS

310

Mepronil

灭锈胺

GC-MSMS

311

Metazachlor

吡唑草胺

GC-MSMS

312

Methacrifos

虫螨畏

GC-MSMS

313

Methidathion

杀扑磷

GC-MSMS

314

Methylpentachlorophenyl
sulfide

五氯硫代苯甲醚

GC-MSMS

315

Metolachlor

异丙甲草胺

GC-MSMS

316

Mirex

灭蚁灵

GC-MSMS

317

Molinate

草达灭

GC-MSMS

318

Myclobutanil

腈菌唑

GC-MSMS

319

Napropamide

敌草胺

GC-MSMS

320

Nuarimol

氟苯嘧啶醇

GC-MSMS

321

Oxadiazon

噁草酮

GC-MSMS

322

Oxadixyl

噁霜灵

GC-MSMS

323

Oxyfluorfen

乙氧氟草醚

GC-MSMS

324

Paclobutrazol

多效唑

GC-MSMS

325

Parathion

对硫lin磷

GC-MSMS

326

Parathion-methyl

甲基对硫lin磷

GC-MSMS

327

Penconazole

戊菌唑

GC-MSMS

328

Pendimethalin

二甲戊灵

GC-MSMS

329

Penflufen

氟唑菌苯胺

GC-MSMS

330

Pentachloroaniline

五氯苯胺

GC-MSMS

331

Permethrin

氯菊酯

GC-MSMS

332

Phenothiol

酚硫杀

GC-MSMS

333

Phenothrin

苯醚菊酯

GC-MSMS

334

Phenthoate

稻丰san散

GC-MSMS

335

2-Phenylphenol

2-苯基苯酚

GC-MSMS

336

Phorate

甲拌lin磷

GC-MSMS

337

Phosalone

伏杀硫磷

GC-MSMS

338

Phosmet

亚胺硫lin磷

GC-MSMS

339

Pirimiphos-ethyl

乙基虫螨磷

GC-MSMS

340

Pirimiphos-methyl

甲基嘧啶磷

GC-MSMS

341

Procymidone

腐霉利

GC-MSMS

342

Prometryn

扑草净

GC-MSMS

343

Propaphos

丙虫磷

GC-MSMS

344

Propiconazole

丙环唑

GC-MSMS

345

Prothiofos

丙硫磷

GC-MSMS

346

Pyraclofos

吡唑硫磷

GC-MSMS

347

Pyraflufen-ethyl

吡草醚

GC-MSMS

348

Pyrazophos

吡菌磷

GC-MSMS

349

Pyridaphenthion

哒嗪硫磷

GC-MSMS

350

Pyrimethanil

嘧霉胺

GC-MSMS

351

Pyrimidifen

嘧螨醚

GC-MSMS

352

Pyriproxyfen

吡丙醚

GC-MSMS

353

Pyroquilon

咯喹酮

GC-MSMS

354

Quinalphos

喹硫磷

GC-MSMS

355

Quintozene(PCNB)

五氯硝基苯

GC-MSMS

356

Salithion

水杨硫磷

GC-MSMS

357

Sedaxane

氟唑环菌胺

GC-MSMS

358

Silafluofen

氟硅菊酯

GC-MSMS

359

Tebuconazole

戊唑醇

GC-MSMS

360

Terbufos

特丁硫lin磷

GC-MSMS

361

Tetraconazole

四氟醚唑

GC-MSMS

362

Tetradifon

三氯杀螨砜

GC-MSMS

363

Tetramethrin

胺菊酯

GC-MSMS

364

Thenylchlor

甲氧噻草胺

GC-MSMS

365

Thifluzamide

噻呋酰胺

GC-MSMS

366

Thiometon

甲基乙拌lin磷

GC-MSMS

367

Tolclofos-methyl

甲基立枯磷

GC-MSMS

368

Triadimefon

三唑酮

GC-MSMS

369

Triadimenol

三唑醇

GC-MSMS

370

Triazophos

三唑磷

GC-MSMS

371

Tridiphane

灭草环

GC-MSMS

372

Triflumizole

氟菌唑

GC-MSMS

373

Trifluralin

氟乐灵

GC-MSMS

374

Vinclozolin

乙烯菌核利

GC-MSMS

 


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